Plasmachemical reactions are studied in rf and microwave discharges. Plasma polymerization is used for the deposition of selective permeable thin films, protective coatings and humidity detectors. The depositions of hard diamond-like carbon, boron nitride, SiOx and SixOyNz thin films have been conducted using a great variety of plasma-chemical methods. Reactions in nitrogen afterglow are studied by spectroscopical and electron spin resonance methods. An efficient restoration method of ancient excavated objects in high frequency plasma has been successfully developed and applied. A new type of ozonizer with a discharge electrode has also been developed.
Plasma diagnostic methods during the plasma-chemical reactions are used for understanding the kinetics of the plasma reactions. A new, quick spectroscopic method of rotational temperature determination based on the low resolution emission spectrum of N2 was developed as well. The Fabry-Perot interferometer is effectively used for spectroscopical study of the low-temperature plasma. At present, a fully automated experimental set-up with the RC 150 (Burleigh, USA) interferometer is available. This interferometer is controlled by microcomputers and uses the piezoeffect for scanning the line profile. The parameters of plasma as the temperature of neutral particles and the density of charged particles are evaluated from these profiles. Probe and microwave methods are used for these purposes as well. A new method for the detection of hydrocarbon traces in pure nitrogen flow was deleloped. This method is based on spectroscopical measurement of CN spectra. The kinetic constants for reactions in low temperature plasma are measured in a remote microwawe plasma reactor by means of electron spin resonance.
Electrical and power characteristics of discharges are determined and electrical discharges and plasma-chemical processes are studied using computer simulation.
The other research activity of the department is the investigati- on of the properties of thin films prepared by means of plasma-chemical deposition and vacuum evaporation. In particular, electrical and sorption properties of dielectric and metal thin films are studied for practical application. In addition, some selective sensors suitable for detection of various gases have also been developed. Thin films used in the optical industry are prepared here as well.
The Department has established archives for programs, data, papers etc. in physics (mainly for plasmaphysics). These archives are located at computer ftp.muni.cz in the directory pub/muni.cz/physics. These archives can be reached by an anonymous FTP or by gopher server gopher.muni.cz. At the present time, some programs for PC and some cross sections for electrons can be found in the archives. The Department would like to collect programs for calculations in physics (mainly for PC).
The Department would also like to collect physical constants and experimental data (e.g. cross sections and swarm parameters ters), which are important for other calculations or for comparison with the results of others studies. Interested scholars are invited to send us preprints and reports for these archives. All files in the archives are public domain and can be obtained using computer network.
Your contributions can be sent by anonymous FTP to directory pub/muni.cz/incoming/physics. Please, send an e-mail about it to trunec@sci.muni.cz.
The Department participates in the education of teachers and specialists in physics, biophysics and engineering optics. Currently in the plasma physics 5 4th year students 5 5th years students are working on their diploma thesis at the Department.
Department of Physical Electronics Faculty of Science Masaryk University Kotlarska 2 611 37 Brno Czech Republic phone: +420-5-41129426 fax: +420-5-41211214 Head of the Department : prof. RNDr. Jan Janca, DrSc. Professors : prof. RNDr. Vratislav Kapicka, DrSc. Senior Lecturers : doc. RNDr. Zdenek Ondracek, CSc. doc. RNDr. Ladislav Sodomka,CSc. doc. RNDr. Antonin Talsky, CSc. doc. RNDr. Jiri Drimal, CSc. Lecturers : RNDr. Ctibor Tesar, CSc. RNDr. David Trunec, CSc. Research Assistants : RNDr. Antonin Brablec, CSc. Ing. Josef Kratochvil RNDr. Jiri Novak doc. RNDr. Vladimir Vetterl, CSc.
Iva Gurecka: Determination of temperature of microwawe discharge from molecular spectra, Vilem Zvonicek: Study of recombination of atomic oxygen and reactions with TEOS, Lenka Zajickova: Optical properties of carbon based thin films, Pavel Krystof: Plasmochemical Deposition of SixOyCz thin films.In Academic year 1993/1994 the following PhD theses were presented and defended :
Pavel Zemanek: Mode Polarization Stability in Lasers with Internal Mirrors and Laser Cooling of Atoms in a Strong Standing Gaussian Wave.
Grant No 202/93/2118 : Plasmachemical Processes in Plasmas and on the Boundary with Solid State, Grant Applicant - J.Janca Grant No 202/93/1022 : Generation of Non-Equilibrium Plasma for Study of Plasmachemical Processes in flowing Media at Atmospheric Pressure, Common grant with Institute of Plasmaphysics Czech Academy Prague. Grant Joint Applicant - J. Janca Grant No 202/94/0490 : The Study of Processes Arising in Using the Plasmochemical Method for Restoring and Conserving Archeological and Museum Objects. Grant Applicant - J. Janca Grant No 202/94/ : Experimental and Theoretical Study of Plasmachemical Systems with Plasma Jet, Common Grant with Department of Vacuum Physics, MFF UK, Prague. Grant Applicant - V. Kapicka Grant No 202/94/1228 : Investigation of Physical and Chemical Processes in Glow Discharge under Atmospheric Pressure. Grant Applicant - J. Drimal
Grant No 1203-1994 : Lectures and Summer School on Elementary and Chemical Processes in Plasma. Professors from abroad (France, Germany, Russia, Slovakia, Netherlands). Grant Applicant - J. Janca Grant No 1222-1994 : A Common Laboratory for the Development of Diagnostics and Depollution Methods of Organic Pollutants. Grant Applicant - J. Janca Grant No 1169-1994 : Usage of Computers in Physical Laboratory Measurements, Grant Applicant - V. Kapicka Grant No P264/16/1994 : The Implementation of Modern Measuring Methods for Teaching at Secondary Schools, Grant Applicant - Z. Ondracek Grant No 1216-1994 : The Creation of Archives of Programs and Textbooks for the Teaching of Physics in the Computer Network of Masaryk University, Grant Applicant - Z. Ondracek
PEGAS (Advanced Material Technology), collaboration with VUT, Brno NCC JEP No 2262 (New Curricula and Courses in Engineering Education), collaboration with CVUT, Praque PECO - (FSDTA) 08469 contract No ERBCIPACT 924034 : Fundamental Studies of Discharges in View of Their Technological Applications, coordinator Prof. A.M. Pointu, University of Paris Sud Copernicus project No 972P sec. 3, (1995-1997) : Barrier coatings in the packaging industry, coordinator Dr. M. Hopkins, University of Dublin
Drimal J. and Trunec D., Monte Carlo Method - foundation and aplications in physics, Dep. of Phys. Electronics, Brno 1994
[1] Janca J.,Talsky A.,Krcma F.,Ricard A.,Hochard L.,CN Chemilu- miniscence in N2+CH4 microwave afterglow at very low tempe - ratures, Plasmachemistry and Plasmaprocessing, 14, 197(1994) [2] Teply J.,Dressler M.,Janca J.,Tesar C.,Destruction of Organic Compounds in HF discharge Plasma at Reduced Pressure, Plasma- chemistry and Plasmaprocessing, in print [3] Janca J.,Talsky A.,Zvonicek V., Kinetics of O2+TEOS Gas-Phase Chemical Reactions in a Remote Microwave Plasma Reactor with ESR, Proc. ESCAMPIG 1994, Noordwijkerhout, The Netherlands, p.364 [4] Janca J.,Solc M.,Vetesnik M., Laboratory Spectra of C60 and Related Molecular Structures, Proc. Symp. Boulder, Colorado NASA Conf. Public. 10144, p.53