Project information
Coordination oligomers and polymers of zinc triad with dithiolates

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Project Identification
Project Period
1/2007 - 12/2009
Investor / Pogramme / Project type
Czech Science Foundation
MU Faculty or unit
Faculty of Science
coordination polymers, oligomers, ligands, dithiolates, metal complexes

The project is aimed at the synthesis and characterization of new molecular, oligomeric, and polymeric compounds of the zinc triad with selected dithiolates. The syntheses will start from mono-, bi-, and trifuctional dithiolates, which are able to form coordinated polymeric arrays. Their compositions, structures, and physicochemical properties will be studied by means of NMR, IR and Raman spectroscopy methods, X-ray diffraction, porosity will be examined by adsorption isotherms of gases, and optical properties will be investigated by time-resolved and steady-state luminescence spectroscopies. The results will serve as a feedback for the modification of starting ligands and other molecular precursors in the search for optimal pore characteristics and optical properties of the studied materials.


Total number of publications: 2

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